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Multimetallic Gold–Iron Compounds Based on Aurated Ferrocenes

Meyer, Nadine ; Schucht, Heike ; Lehmann, Christian W. ; Weibert, Bernhard ; Winter, Rainer F. ; Mohr, Fabian

European journal of inorganic chemistry, 2017-01, Vol.2017 (2), p.521-526 [Periódico revisado por pares]

Weinheim: Wiley Subscription Services, Inc

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  • Título:
    Multimetallic Gold–Iron Compounds Based on Aurated Ferrocenes
  • Autor: Meyer, Nadine ; Schucht, Heike ; Lehmann, Christian W. ; Weibert, Bernhard ; Winter, Rainer F. ; Mohr, Fabian
  • Assuntos: Crystals ; Cyclic voltammetry ; Derivatives ; Diffraction ; Electrochemistry ; Ferrocenes ; Gold ; Multimetallic compounds ; Single crystals ; Spectroscopy ; Voltammetry ; X-ray diffraction ; X-rays
  • É parte de: European journal of inorganic chemistry, 2017-01, Vol.2017 (2), p.521-526
  • Notas: ObjectType-Article-1
    SourceType-Scholarly Journals-1
    ObjectType-Feature-2
    content type line 23
  • Descrição: A family of aurated ferrocenes was prepared by a transmetallation reaction using ferroceneboronic acid derivatives. With this method, multimetallic ferrocenyl complexes [FcAu(PPh3)] {Fc = (η5‐C5H4)FeCp} and [(µ‐P‐P)(AuFc)2] {P‐P = dppe, dppf}, as well as 1,1′‐diaurated ferrocenes [Fe(η5‐C5H4AuPPh3)2] and [Fe{(η5‐C5H4Au)}2(µ‐P‐P)] {P‐P = dppe, dppf}, were obtained in high yields as air‐stable orange materials. The compounds were characterised by spectroscopic methods, cyclic voltammetry and single‐crystal X‐ray diffraction. The reactivity of the dinuclear gold(I) complex in oxidative addition reactions is also reported. A family of multimetallic ferrocenyl complexes were prepared by transmetallation using boronic acid derivatives. The compounds were characterised by spectroscopic methods, cyclic voltammetry and single‐crystal X‐ray diffraction. The reactivity of the dinuclear gold(I) complex in oxidative addition reactions is also reported.
  • Editor: Weinheim: Wiley Subscription Services, Inc
  • Idioma: Inglês
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