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Switchable on-off spin-crossover properties of iron() compounds by trimming intermolecular hydrogen bonds

Li, Na ; Xue, Jin-Peng ; Liu, Jing-Lin ; Wang, Yao-Yao ; Yao, Zi-Shuo ; Tao, Jun

Dalton transactions : an international journal of inorganic chemistry, 2020-01, Vol.49 (4), p.998-11 [Periódico revisado por pares]

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Título:
Switchable on-off spin-crossover properties of iron() compounds by trimming intermolecular hydrogen bonds
Autor: Li, Na ; Xue, Jin-Peng ; Liu, Jing-Lin ; Wang, Yao-Yao ; Yao, Zi-Shuo ; Tao, Jun
Assuntos: Chemical bonds ; Crossovers ; Crystallography ; Hydrogen bonds ; Single crystals
É parte de: Dalton transactions : an international journal of inorganic chemistry, 2020-01, Vol.49 (4), p.998-11
Notas: 1965898-1965904
For ESI and crystallographic data in CIF or other electronic format see DOI
10.1039/C9DT04685B
Electronic supplementary information (ESI) available: Synthesis and additional tables and figures. CCDC
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
Descrição: Reversible single crystal-to-single crystal transformations from [FeL 2 (NCS) 2 ]·3MeOH ( 1·3MeOH , L = 2-(anthracen-10-yl)-1 H -imidazo[4,5- f ][1,10]phenanthroline) to 1 and 1·2H 2 O were reported, which were accompanied by on-off switching of the spin-crossover properties. Spin crossover on-off switching is realized by reversible single crystal-to-single crystal transformations, 1·3MeOH 1 1·2HO .
Editor: England: Royal Society of Chemistry
Idioma: Inglês

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